Showing posts with label akali. Show all posts
Showing posts with label akali. Show all posts

Sunday, 7 February 2016

Group 1 - The Alkali Metals

What are the elements?

The elements in Group I are:

  • Lithium
  • Sodium
  • Potassium
  • Rubidium
  • Caesium 
  • Francium (radioactive)
For IGCSE you need to be aware of all of these metals, but you only need to know the details about the first three.

All of these metals have to be kept under oil, because they're very reactive, so they can't come into contact with air or water.



Properties of lithium, sodium and potassium:

  • Soft metals
  • Good conductors of electricity
  • Low densities
  • Low melting points
  • When freshly cut by a knife, they have a shiny surface
  • Burn in air, forming white oxides, the white oxides form alkaline solutions of the metal hydroxide when dissolved in water
  • React vigorously with water, making an alkaline solution of the metal hydroxide and hydrogen gas
  • React vigorously with halogens (e.g. chlorine) forming metal halides (e.g. sodium chloride)
  • Potassium reacts the most with water, then sodium and lithium reacts the least with water
Gradual changes (like the one above) are called trends, trends allow chemists to predict things about elements that they have not yet observed.

The further down the group you go, the more reactive the metals are, so obviously francium is the most reactive. For more information on this look at the post on The Periodic Table 

When the Group I elements react, they loose an electron, becoming more stable because their electron configuration is now the same as that of a noble gas. 

The Periodic Table and Electronic Structure

History

The Periodic Table was invented in 1969 by the Russian scientist Dmitri Mendeleev (at that time, Professor of Chemistry at St. Petersburg University).

He arranged the 63 elements (all that were known at that time) by increasing atomic mass, leaving gaps where he predicted that elements, that were undiscovered at that time, would fit into the table.

Mendeleev arranged is so that elements that have similar properties are in the same groups.


This is the Periodic Table supplied by www.cie.org.uk
So this is probably the most reliable one you can find!


Key Terms


Groups = the vertical columns in the Periodic Table

Periods = the horizontal rows in the Periodic Table

Modern Periodic Table

There are currently 118 known elements!

Elements are arranged by proton number in the modern Periodic Table and elements with similar priorities are still in the same groups.


Groups:

There are eight groups of elements:

  • Group I
  • Group II
  • Group III
  • Group VI
  • Group V
  • Group VI
  • Group VII
  • Group 0 (sometimes known as Group VIII)
Group I is known as the alkali metals, Group II as the alkaline earth metals, Group VII as the halogens and Group 0 as the inert gases or noble gases.

The big block of elements between Groups II and III are the transition metals.


Periods:

The periods are numbered 1-7, going down the periodic table.

Across each period the properties of the elements change:

Courtesy of Bryan Earl and Doug Wilford's
Cambridge IGCSE Chemistry Third Edition


Metals and non-metals:

The bold line that starts beneath boron divides the Periodic Table into two parts.
The elements on the left of the line are metals and the elements on the right are non-metals.
Metalloids is the name given to the elements that are on this dividing line, they are metals that have properties of both metals and non-metals.



Electronic Structure and The Periodic Table

The group that an element is in determines how many electrons it has in it's outer shell.

N.B. This does not apply to the elements in Group 0, they have either 2 or 8 electrons

So the elements in Group I have 1 electron in their outer energy level and the elements in Group II have 2 electrons in their outer energy level, and so on and so on.

As you move down a group, the metallic characteristics of the elements increases, this happens because the outer energy shell becomes further away from the nucleus, as do the electrons in it. So there's less attraction between the outer energy shell's electrons and the nucleus, due to distance, so the electrons in the outer shell are easier to loose.
This doesn't happen in Group VII, in this group the reactivity DECREASES as you go down the group.